Friday, March 27, 2020

Time As A Determinate Of Final Product In A Dehydration Reaction Essay Example For Students

Time As A Determinate Of Final Product In A Dehydration Reaction Essay Time as a Determinate of Final Product in a Dehydration ReactionRobert Simack, Department of Chemistry and Biochemistry, University of Alaska Fairbanks, Fairbanks, Alaska. Abstract: This study involved acid dehydration of 2-methylcyclohexanol. The results varied depending on the time elapsed after initial reaction. I attempted to prove the Evelyn Effect, which stated that over a period of time the products of the aforementioned reaction will beobserved to change volume so that those products formed by a cis isomer of 2-methylcyclohexanol will form first. However, once all molecules in the cis isomer undergo reaction the remaining trans configured 2-methylcyclohexanols will proliferate during the latter period of the reaction. I also postulated as to the possible formulation of 1-ethylcyclopentene, and to the cause of such an event. We will write a custom essay on Time As A Determinate Of Final Product In A Dehydration Reaction specifically for you for only $16.38 $13.9/page Order now Introduction: After researching acid-catalyzed dehydration reactions (McMurray) and background on the Evelyn Effect (Clausen) I hypothesize that the cis isomer of 2-methylcyclohexanol will react via an E1 type process forming 1-methylcyclohexene according to predictions from Zaitzevs rule (Lehman). This should be due to the fact that the cis isomer has 2 anti-coplanar hydrogens. These two hydrogens should make the molecule more reactive. The trans isomer, with only one anti-coplanar hydrogen, should be slower to react and will form a 3-methylcyclohexene. In addition the 1-ethylcyclopentene will be formed from both the cis and trans isomers but only if the hydroxyl group is in an equatorial position. In that position electrons from the ring may attack the alcohol directly from behind pushing it off the ring and forming a five-membered ring instead. Results ; Discussion: An NMR (300MHz) spectra of the original reagent and the three fractions provided a huge amount of information in support of my hypothesis. Both cis and trans isomers were present in the spectra for the original material as well as for the first two fractions. The alcohols hydrogen showed up at approximately 3.79 and 3.1 for cis and trans respectively. In the spectra for pure starting material (ref: Jim Starr /Steve Standish NMR 24 March, 2000) cis isomers of starting material comprised only 25% of the sample compared to 75% of trans as observed in the integration of peaks. In the spectra for fraction one a 3:1 ratio of trans to cis was observed. In the spectra of fraction two the cis isomer nearly disappeared; the ratio was roughly 6:1 trans/cis. Finally, in the spectra of the third fraction the cis isomer was absolutely imperceptible while the integration of trans was nearly twice that of the integration from fraction one. These spectra show that cis reacted fi rst and was quickly consumed by the reaction leaving trans isomers to finish the reaction. Because it is known that the reaction with cis starting material caused both 3-methylcyclohexene and 1-methylcyclohexene I postulated that the foremost product of the latter stages of the reaction must be 3-methylcyclohexene, which is the sole product of the trans reaction (McMurray, chap. 11.12). In addition to the cis and trans peaks the peaks for both 3-methylcyclohexene and 1-methylcyclohexene could be found on the spectra at 5.7 and 5.4 respectively. The NMR showed that the integration of 1-methylcyclohexene dropped only slightly throughout the reaction while the integration of 3-methylcyclohexene increased nearly tenfold. The findings from the spectra prove the hypothesis that the cis reaction will go the fastest followed by the trans because as the cis is consumed its peak at 3.79 will decrease as well as the peak for 1-methylcyclohexene due to termination of that products formation. Also, peaks for 1-ethylcyclopentene begin to show in the spectra for the second fraction and increase in size (area beneath the peak) by the spectra of the third fraction. At the root of this phenomena is steric hinderance. Both the cis and trans isomers will form 1-ethylcyclopentene (fig. 1). However, because of steric hinderance the trans isomer is favored to form the 1-ethylcyclopentene. This fact will explain why more of the pentene shows up in the third fraction. .ucb0d8b367cbe537fb5a26519d8487950 , .ucb0d8b367cbe537fb5a26519d8487950 .postImageUrl , .ucb0d8b367cbe537fb5a26519d8487950 .centered-text-area { min-height: 80px; position: relative; } .ucb0d8b367cbe537fb5a26519d8487950 , .ucb0d8b367cbe537fb5a26519d8487950:hover , .ucb0d8b367cbe537fb5a26519d8487950:visited , .ucb0d8b367cbe537fb5a26519d8487950:active { border:0!important; } .ucb0d8b367cbe537fb5a26519d8487950 .clearfix:after { content: ""; display: table; clear: both; } .ucb0d8b367cbe537fb5a26519d8487950 { display: block; transition: background-color 250ms; webkit-transition: background-color 250ms; width: 100%; opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #95A5A6; } .ucb0d8b367cbe537fb5a26519d8487950:active , .ucb0d8b367cbe537fb5a26519d8487950:hover { opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #2C3E50; } .ucb0d8b367cbe537fb5a26519d8487950 .centered-text-area { width: 100%; position: relative ; } .ucb0d8b367cbe537fb5a26519d8487950 .ctaText { border-bottom: 0 solid #fff; color: #2980B9; font-size: 16px; font-weight: bold; margin: 0; padding: 0; text-decoration: underline; } .ucb0d8b367cbe537fb5a26519d8487950 .postTitle { color: #FFFFFF; font-size: 16px; font-weight: 600; margin: 0; padding: 0; width: 100%; } .ucb0d8b367cbe537fb5a26519d8487950 .ctaButton { background-color: #7F8C8D!important; color: #2980B9; border: none; border-radius: 3px; box-shadow: none; font-size: 14px; font-weight: bold; line-height: 26px; moz-border-radius: 3px; text-align: center; text-decoration: none; text-shadow: none; width: 80px; min-height: 80px; background: url(https://artscolumbia.org/wp-content/plugins/intelly-related-posts/assets/images/simple-arrow.png)no-repeat; position: absolute; right: 0; top: 0; } .ucb0d8b367cbe537fb5a26519d8487950:hover .ctaButton { background-color: #34495E!important; } .ucb0d8b367cbe537fb5a26519d8487950 .centered-text { display: table; height: 80px; padding-left : 18px; top: 0; } .ucb0d8b367cbe537fb5a26519d8487950 .ucb0d8b367cbe537fb5a26519d8487950-content { display: table-cell; margin: 0; padding: 0; padding-right: 108px; position: relative; vertical-align: middle; width: 100%; } .ucb0d8b367cbe537fb5a26519d8487950:after { content: ""; display: block; clear: both; } READ: Coordinate WSH Management System with Legal Compliance EssayFinally, a tiny peak showed at 4.6 in every fractions spectra indicating the presence of methylenecyclohexane. This product formed from the original product by acid catalyst. Experimental: An apparatus was constructed with a round bottom flask topped by a claisen adaptor in which was placed a thermometer and a condensing tube. In the apparatus 150mmole of 2-methylcyclohexanol was mixed with 5mL H3PO4 and distilled. The distilled liquid was collected in three tubes, at approximately 4mL per tube, labeled fraction 1, 2 and 3. Each fraction was placed in a centrifuge tube and combined with 4mL saturated NaHCO3. The aqueous layer was removed and MgSO4 was added for a final separation. The solid and aqueous layers were then removed and the final product was combined with CDCL3 in an NMR tube in preparation for spectra. The liquid remaining in the original apparatus was put through the separation process described above. However, instead of CDCL3 as a spectrum reagent we used CH2CL2. Also, an NMR was not performed on the remaining liquid but instead a GC. Figure 1: Reactions of cis and trans isomers of 2-methylcyclohexanol during acid-catalyzed dehydration. BibliographyClausen, Tom, ?Organic Chemistry 324 Lecture,? Univeristy of Alaska, Fairbanks, March 20, 2000. Lehman, John W., Operational Organic Chemistry, 3rd ed., New Jersey: Prentice-Hall, Inc., 1999. McMurry, John, Organic Chemistry, 4th ed., California: Brooks/Cole Publishing, 1996. Science Essays

Friday, March 6, 2020

War and The Holocaust essays

War and The Holocaust essays As the old saying goes, there are always two sides to every story. This rings true for war and the Holocaust. There were individuals who were in support of war, albeit their knowledge of its destructive powers, and there were some people who saw its disadvantages through their own eyes, and were therefore vehemently against it. One side saw war and the Holocaust as a positive step towards progress and development, while another side saw unjust destruction and death. Both Bernhardi and Mussolini saw benefits of war for European culture, but Remarque, Monks and Graebe saw, through their own actual experiences, that the benefits acquired through war did not outweigh the disadvantages that it unleashed. In his essay, General Friedrich Von Bernhardi defended the act of war, saying that humankind cannot escape it. He says that, ...the struggle between nations is inevitable... (Bernhardi 177). Furthermore, he says that the development of a country could be, for the most part, attributed to battle. Bernhardi mentions that although war has its setbacks, it is also a creative and purifying power (Bernhardi 177), and a life-giving principle (Bernhardi 178). In addition, Bernhardi admits that war temporarily disturbs industrial life, interrupts quiet economic development...and emphasizes the primitive brutality of man. (Bernhardi 177), but says that war is a need that man has to heed, a biological necessity of the first importance (Bernhardi 177) that cannot be taken away from society. He further upholds his argument by defining the search for peace and the abolishment of war as a journey for the weak and cowardly. According to Bernhardi, ...this desire for peace has rendered most civiliz ed nations anaemic... (Bernhardi 177). Moreover, Bernhardi argues that war has greater benefits. According to Bernhardi, war will furnish...a nation with favourable vital conditions.....

Wednesday, February 19, 2020

What do you consider to be the major issues facing pblic education Essay

What do you consider to be the major issues facing pblic education today. Address one of the issues in depth, outlining possible causes, effects and resolutions - Essay Example Furthermore, recent budget cuts have even taken place as a result of economic recession. The consequence of decline in public education budget is that teachers are not being paid on time and due to this several teachers have stopped teaching at public schools. The qualities of education being provided to those who are dependent on public schools have even declined as a result of loss of quality teachers. One solution is to increase the budgets for public education by decreasing the budgets allocated to other sectors. Another solution is online education as it requires lower amount of investment (Christensen 1). A third solution is to provide underdeveloped teachers with appropriate training so the quality of education can be increased. One of the significant issues experienced by public education is decrease in the allocation of budget towards education sector. This is a major problem faced by modern day society as due to this issue, the future of society is at stake. Various solutions such as adoption of online education can be implemented to solve this

Tuesday, February 4, 2020

Michigan agricultural college a dream fullfiled Essay

Michigan agricultural college a dream fullfiled - Essay Example In 1850, the state constitutional convention called for the foundation of an Agricultural School under the provision of Article 13, Section 11 – the Morrill Act enacted under Abraham Lincoln’s administration. Interestingly, it was first suggested that this Agricultural School would be part of the University of Michigan. In fact, then-president Henry Tappan lobbied for this school to be built in UM’s own Ann Arbor. However, John C. Holmes of the Michigan State Agricultural Society opposed this, on the ground that the school’s students may end up being neglected by UM. Luckily for him, then-Michigan Governor Kingsley S. Bingham saw things his way, mandating a bill commissioning the establishment of what was then called the Agricultural College of the State of Michigan. Eleven years later would be a moment in history for the school – it saw its first batch of graduates, as well as the Michigan Legislature that allowed it to offer four-year curriculum c ourses and grant degrees on par with more established universities. The beginnings of the Agricultural College were surprisingly humble. Under its first president, Joseph Williams, a member of Harvard’s Phi Beta Kappa in addition to being both an accomplished farmer and attorney, it started out with only three buildings and five professors, as well as a student body of 63. Luckily, Williams made the best of the situation, hiring a host of competent professors in the college’s first year. These professors then proceeded to set up sophisticated science laboratories in its College Hall, complete with equipment such as microscopes which were then thought to be state-of-the-art. Needless to say, Michigan Agricultural College flourished under President Williams’s tenure; even relatively early on in its existence, it boasted a wide array of theoretical and practical academics. The Michigan state legislature passed a bill in 1855, which

Monday, January 27, 2020

The Life of Ethan and Zeena Today

The Life of Ethan and Zeena Today If Ethan and Zeena lived in todays modern world their lives would be different because gender roles, social customs, and divorce customs are different from the nineteenth century. Reasons for Isolation during the nineteenth century Environmental factors Technology Life in the nineteenth century Womens roles Marriage responsibilities Education Work Mens roles Marriage responsibilities Education Work Divorce Social customs rates Life in Todays World Womens Roles Mens Roles Divorce Social customs Zeenas nineteenth century life vs. her modern life Married life Financial situation Education Social life Ethans nineteenth century life vs. his modern life Married life Financial situation Education Social life Zeenas and Ethans Lives compared to Todays Modern Age In Edith Whartons Ethan Frome, Ethan and Zeena suffer because of the social expectancy during the nineteenth century. People who lived in rural areas during the nineteenth century were very isolated and had little interaction with neighbors. Life during the nineteenth century was based on social status and customs. Marriage was believed to be a womens main purpose in life. Women had no choice, but to seek marriage because women had little opportunities to work and were expected to live from a husbands income. If Ethan and Zeena lived in todays modern world their lives would be different because gender roles, social customs, and divorce customs are different from the nineteenth century. Isolation played a major factor in the characters lives during the nineteenth century. Isolation was very frequent in rural areas. People who lived in rural areas had little knowledge of social interaction. One reason for isolation in rural communities was population decline (Frome 126). Population had decreased because people moved to larger cities were more jobs and better technology was offered. Farmers who decided to stay in their farms with their families, lived in smaller, emptier communities (Frome 126). People ended up very isolated because the environment was lonely with very few residents. People were not able to interact because the isolation in the environment was very depressing. Married couples spent most of the time with each other in isolated farms. Life was very depressing for people who lived in rural communities. Secondly, technology was one of the causes for isolation in rural New England. Ethan Frome states: Both the telephone and automobile would greatly reduce feelings of isolation once they came to rural areas; people would be able to converse with neighbors much more easily and travel to nearby towns. However, it took a long time for these inventions to reach even middle-class homes in isolated areas such as the one in Ethan Frome. In fact, phone and automobiles would not come to many farm families until the mid-1910s, after the time of the novel.(128) People were very isolated in rural New England because they did not have many luxuries we have today like the telephone, cars, and computers. Life during the nineteenth century was very oppressing for men and women. Gender roles were very precise during that era. According to Elizabeth Ammons, women were not allowed to vote during the Ethan Frome era (n.pag.). Women faced discrimination during the nineteenth century because men were considered the authority of the household. Women depended on men for income, food, and shelter (Frome126).Women roles during the nineteenth century were very different from todays modern world. Women had to deal with many hard situations. For example, A wifes responsibilities included a comfortable home, performing household chores, and bearing and caring for children. She was expected to remain chaste, modest and frugal in household expenses and to abstain from conduct that reflected badly on her home or her husbands good name (Frome 126). Women were treated like animals because they were not allowed to have a decent human life. Women did not have the opportunity in making decisions. Life for women was very sad because women had no rights on their persona. Women had a very hard role in life because they were expected to follow the gender roles that society imposed. Education is another factor that affected womens lives during the nineteenth century. Women rarely had an education and if they did they were not allowed to work (Frome126). If women did not have an education there was no way they could make a living without a man. Women felt obligated to their husbands because they had no way of earning an income. Womens only education included housewife duties, which were the only things they knew how to do. Mens roles were very significant in rural New England. Men had big responsibilities because It was the duty of husbands like Ethan Frome to provide their families with the necessities of life, to treat their wives with courtesy, and to behave responsibly in financial affairs (Frome126). The mans main purpose was to take care of his wife economically. Men knew that a woman could not live by herself during that era; there was no way she could survive by herself. Men felt obligated to his wife because society imposed it. Many men feared of violating social norms because they treated social norms as laws. Men thought if they violated societal rules they were breaking the law. It is known that men were the ones who usually had an education and if they did not, they usually worked outside of the home like in Ethans case. Men had more opportunities of receiving an education than women. Many critics say that during the Ethan Frome era, divorce was rare and socially criticized. Many couples who did not love each other felt forced to live with one another because of societal rules. Many couples during the Ethan Frome era did not divorce because divorces became permissible after that era. Life in todays world is very different from the nineteenth century. Today womens roles are not like back then. In todays world women have the same rights as men. There are many women that decide living in singlehood. Many women live better lives in singlehood because some women are not wife like. Women do not depend on men for a living. Womens roles in todays era do include housewife duties but not all women work as housewives. Many women today are the ones who provide the family financially and some men do the duty of a housewife. There are also women who are single mothers that provide for their children by themselves. Many women in todays world decide to receive an education and end up receiving high salaried jobs. Today, there are laws that prohibit job discrimination because of gender, race, or color. Many women today have better work positions than males. In todays modern world women are admired for working outside of home because they also perform the duty of a housewife. Mens roles are similar and different from the early nineteenth century. Some still feel obligated to provide for their families financially, and others do not. In todays modern world men do not feel obligated to stay with a person they do not love. Men do not have the same responsibilities like in Ethans case. Men know that a woman can sustain herself without him. Mens marriage responsibilities include working and providing family with love and necessities. Education for men is still viewed the same like in the nineteenth century. Many men attend school to pursuit a degree. Men in todays world are offered different types of jobs. People without an education can also have a decent living. Divorce is not seen rare in todays world. Divorces occur almost every day. Women do not feel obligated to stay married because they do not depend on a mans income for a living. Many couples divorce after a couple of months or even days. Divorce is not socially criticized like in the early nineteenth century. People think of divorce as something natural that occurs every day. Divorce rates keep on rising because some people marry too early, without having nurtured their relationship. Some people today do not take a marriage as something serious that lasts for life. Zeenas life would be different if she lived in todays modern world. Zeenas life would be different because she seems to be the type of woman that lives in singlehood. Zeena does not seem to be a good marriage partner. Zeena did not comply with a womens responsibility during the nineteenth century. According to Helen Killoran, Zeena only causes Ethan problems by complaining about her health and spending money on medicines (n.pag.). A woman was not supposed to cause her husband any financial problems like Zeena did to Ethan. Zeena believes she does not have to do house hold chores because it is Ethans duty to pay her back for all the caring she did for his parents (Travis n. pag.). Zeena would be better off alone in todays world because she only ruins her partners life by having a negative attitude. Kathy A. Fedorko describes Zeena as an adult incapable of showing or receiving love (57). In todays modern world divorced women can survive without a male partner, Zeena does not need to be stuck with Ethan. Most likely Zeena would be in better health and financially stable. Zeena has good nursing skills which would give her good income in todays world. Zeena would not have economic, social, or matriarchal problems. People today interact with one another all the time. Zeenas social isolation would not be a problem because technology in todays world has been modernized. Ethans life during the nineteenth century is very terrifying. R.B. Hovey states that, Sex among the Ethan Frome people was hardly casual; divorce if not unthinkable, was most unlikely proceeding (n. pag.). It is evident that Ethan did not have sex with his wife because she was always in bed complaining about her health. Ethan suffered in his marriage because Zeena gave him no love or intimacy. Ethan has many matriarchal responsibilities that prevent him from finding happiness with the woman he loves. Ethan feels financially obligated to Zeena because of gender differences and social norms. Ethan knows Zeena depends on him financially, therefore he cannot abandon her. Another obstacle for Ethan is his inability to break social customs. Ethan would not care of breaking social customs in todays world. Lionel Trilling believes Ethan is trapped when he must choose between his habituated duty to his wife and his duty and inclination to the girl he loves (45). Ethans life would have more me aning if he lived in todays modern world. Ethan would not feel forced to live with a woman he does not love. Ethan would have the opportunity of meeting someone who gives him passion and tranquility. Ethan never has tranquility with Zeena because she always finds a way to make his life miserable. Ethan feels socially obligated toward Zeena. Another reason for Ethans miserable marriage is his silence. Ethan is always silent and never expresses his feeling to Zeena. Ethans financial status would also be different in todays world because Ethan would have a degree in engineering, which was one of his dreams. Ethans social life would be better because, life is not isolated like in the nineteenth century. It seems clear that the cause of Ethans isolation is the environment. Ethans house is described as being one of those lonely New England farmhouses that make the landscape seem even lonelier (Wharton 8). The houses in rural New England describe the lives of the citizens. People today interact with one another every day. Ethan always dreamed of living in a big city with big libraries, he could have fulfilled his dreams in todays world. Life during the nineteenth century was very hard because of isolation, gender roles, and responsibilities. Ethan and Zeena would be stable financially and socially because life today is extremely different from the nineteenth century. Ethan and Zeenas marriage was deteriorated because of the environment and social customs during their lifetime. People today must feel lucky to have all the luxuries such as cars and telephones that did not exist during Ethans life.

Sunday, January 19, 2020

Islam, Quran, Sunnah Essay

The paper talks about the importance of the Quran and the Sunnah as the primary sources of Islamic beliefs, practices, and law, and their influence in Muslims daily life Islam. Islam is a religion that was originated when Prophet Mohammad (PBUH) began to spread the teachings of Allah (God of the followers of Islam) in the 7th century. God choose Prophet Mohammad as his last messenger and ordered the Prophet to spread his teachings and to ask everyone to believe in the oneness of Allah and the people who follow Islam are called the Muslims. Quran is the book of God that was revealed to Prophet Mohammad through Angel Jibrael and the Muslims consider the book to be a very Holy Book of God that covers each and every aspect of life and the word Quran stands for recitation. It talks about everything a human being needs to seek guidance for and it tells the right way of how to live your life. When the Quran was revealed, the language it was written in was Arabic, however, now the book is available in all translations so that people can read and understand the true context of the book well and can follow its teachings. The teachings in the Quran differentiate the right from wrong and also tell the benefits of selecting the right path and the consequences of selecting the wrong path. The Muslims who select the right path would always benefit in the world and also in the hereafter i. e. life after death. Quran does not force anyone to adopt the right or the wrong path but it does portray the negative and the positive aspects of the path the Muslims select. As mentioned above, Quran is a complete book of guidance for the Muslims and it covers every aspect of life. To further explain this, I would give some examples of what Quran speaks of. Some of the very basics that Islam as well as other religions also ask the human community to do is to always select the right path that means they should not cheat anyone, they should not lie, they should not betray anyone or should not take the sue share of another person. As said by the Quran and the Prophet Mohammad, the Muslims who will follow the teachings of Islam and implement the etchings of the Quran will always be successful in every way and the most important thing is that Allah (God) will also love such people and this would then result in the worldly reward or the reward of going to Heaven after death. When the Quran was revealed, the companions of Prophet Mohammad used to write down each and every verse of Allah and the Book was later complied and the text is still the same as it was when it was revealed. The Muslims also believe that each and every word is the Book is the word of Allah. Quran is thus very important in shaping up the life of a Muslim and is one of the primary sources of Islamic beliefs. Other than the Quran, the Sunnah is also considered to be one of the primary sources of the Islamic believes. The word Sunnah basically refers to the path that Prophet Mohammad choose to live his life and it includes the traditions he followed, his actions and words, what he practiced. Overall, it basically the way he had chosen to live his life. The Muslims follow the example of the Prophet Mohammad mainly through the Hadiths. Prophet Mohammad did each and everything God asked him to do and led his whole life always by choosing the right path. For instance, Prophet Mohammad taught the Muslims to offer prayers both individually as well as in congregation especially for the men and that is what the Muslims follow today especially on every Friday when all Muslim men go to the mosque to offer the Friday prayers. Since the time of Prophet Mohammad, people have learned how to live in a practical manner and this has been transmitted to their future generations. The Muslims also adopt the living style of the Prophet that includes his habits and style and the way he dealt with the other people. He was always considerate and caring, he always used to forgive others and he always used to be polite with others and this is what the Muslims must inculcate in themselves as well. The Quran also talks about Prophet Mohammad and has commanded the Muslims to follow what the Prophet has taught and to obey the teachings of the Prophet at all times. The significance of Sunnah is moreover also to please God by doing what His most loved Prophet did and to embrace his way of living. Both the Quran and the Sunnah therefore, play a very vital role in shaping up the life of a Muslim and so these have a great influence on the lives of the Muslim community. Work Cited Neusner, Jacob. World Relgions in America: An Introduction. 3rd Edn. Westminster John Knox Press, 2003. Swarup, Ram. Understanding the Hadith: The Sacred Traditions of Islam. 1st Edn. Prometheus Books, 2002. Voorst, Robert. E. V. Anthology of World Scriptures. 6th Edn. Wadsworth Publishing, 2007. Waqner, Walter H. Opening the Qur’an: Introducing Islam’s Holy Book. 1st Edn. University of Notre Dame Press, 2008.

Friday, January 10, 2020

Compare and Contrast: the Story of an Hour and a Rose for Emily

Deriso 1 Daniel Deriso Professor Robert Eastman English 101 4 September 2012 Compare and Contrast: â€Å"The Story of an Hour† vs. â€Å"A Rose for Emily† The two short stories discussed are about two drastically different women both with oppressive men in their lives. In â€Å"The Story of an Hour†, Louise realizes she wished to be free from her marriage. In â€Å"A Rose for Emily†, Emily is yearning to be married. One woman is looking to be loved, and the other is so full of disdain that it kills her. In â€Å"A Rose for Emily†, Emily is being controlled by her draconian father.He will not allow Emily to have contact with other men. When Emily’s father passes away she requests to keep the body, because she is fearful of being so desolate. Emily later kills her boyfriend Homer Barron for trying to leave her, and his body is not discovered until after her death. Whereas, â€Å"The Story of an Hour† is about a woman who wishes the man i n her life is not in her life. The reader can tell from Louise’s thoughts that her spouse is a very stern man. The news of his passing brings her a feeling of overwhelming freedom.Emily never married because her father would not allow it. This fact drives her insane. Her life dream is to be married, but she will end up alone. However, Louise Mallard, who is married, yearns for those bonds to be severed. Her marriage is what inevitably kills her. The stories both end tragically. In both stories the protagonist dies, yet for very different reasoning. Emily kills Homer for trying to leave her. Then she keeps his body with her until she is discovered dead of old age.Louise Mallard believes her husband to be dead, which leaves her bonds of marriage broken. His return causes her so much anguish that she dies of a heart attack. In the end, both women die of their individual ideas of love. Emily has every man she ever loved Deriso 2 die throughout her life. Louise Mallard faces her m ortality when she realizes that her husband is still alive. The stories are both extremely grim. They deal with the themes of love, hate, and loss. Three of the most powerful themes in all of literature.